View notes constants for antoine equation from ceng 3210 at the hong kong university of science and technology. University of groningen vapor pressures of several. The yaws handbook of vapor pressure ebook by carl l. Vaporliquid equilibrium, binary mixture this is an example of px, tx calculating of vaporliquid equilibrium curves for binary mixture vapor mixture of ideal gases liquid ideal mixture obeying roult low constants in antoine equation for vapor pressure binary mixture. Understanding antoine coefficients for vapor pressure leads to numerous critical engineering applications such as pure. Langes handbook of chemistry, mcgrawhill professional. Fitting vapor pressure data with regression application center. Antoine coefficients, 2nd edition delivers the most comprehensive and practical database source for todays petrochemical. In this study, a rangefree method is proposed in order to determine the antoine constants for a given material salicylic acid. So, we need to define temperature range for the antoine parameters, and it is said there is no expolation ability for this scheme. The advantage of this met a rangefree method to determine antoine vapor pressure heat transferrelated equation coefficients using the boubaker polynomial expansion scheme springerlink. The results are also compared with a model previously developed from. The data is both experimentally determined and estimated based on methods developed by the author and other noted experts.
If i calculate vapor pressure at boiling point with these antoine parameters, the difference of estimated vapor pressure should be 760mmhg vary 260mmhg. Jan 22, 2007 vapor pressure of the componants by antoine coefficients posted in packed tower design and operation. This means that you only have to buy a license for one webserver, and then, each coworker in your company can have access to the application simply using a web browser. Understanding antoine coefficients for vapor pressure extends to numerous other practical engineering processes, such as pure components in storage vessels, the concentration of species in vapor, relief valve design, as well as emissions into the environment from exposed liquids. Therefore two sets of coefficients are commonly used. Increased to include over 25000 organic and inorganic compounds, the yaws handbook of vapor pressure. To select multiple items from this box, click on terms while holding down the ctrl key windows or apple key mac. If p 1 1 atm, then t 1 is the normal boiling point, and we can determine the vapor pressure at any other temperature ln p2 p1 vap h r 1 t2 1 t1 vapor pressure and boiling point. Handbook of vapor pressure inorganic compounds and elements. Antoine coefficients, 2 nd edition delivers the most comprehensive and practical database source for todays petrochemical. Antoine coefficients are one of the most important properties to industry processes, and carl yaws provides all the skills necessary for every chemical engineer, both academic and experienced. The content of this database presents a compilation of results for vapor pressure using the antoine equation, and contains an extensible, searchable table with antoine coefficients of over 9,995 compounds. The values of the antoine parameter c are shown to be related to the characteristic frequency of the liquid. The yaws handbook of vapor pressure download ebook pdf.
The yaws handbook of physical properties for hydrocarbons and chemicals. Vapor pressure vapor pressure also referred to as the equilibrium vapor pressure, is the pressure of a vapor in equilibrium with its liquid or solid phase. Yaws handbook of antoine coefficients for vapor pressure. Use features like bookmarks, note taking and highlighting while reading the yaws handbook of vapor pressure. Yaws handbook of vapor pressure, antoine coefficients, 2nd ed. A 10liter cylinder containing oxygen at 175 atm absolute is used to supply o 2 to an oxygen tent. This shopping feature will continue to load items when the enter key is pressed. Yaws handbook of antoine coefficients for vapor pressure 2nd electronic edition details the content of this database presents a compilation of results for vapor pressure using the antoine equation, and contains an extensible, searchable table with antoine coefficients of over 9,995 compounds. Antoine coefficients, 2nd edition the yaws handbook of vapor pressure. Constants for the antoine equation for vapor pressures of pure in p. The yaws handbook of vapor pressure paperback walmart. Assuming a constant temperature of 27 o c, calculate the grammoles of o 2 that can be obtained from the cylinder, using the compressibility factor equation of state when appropriate. You can read online the yaws handbook of vapor pressure antoine coefficients here in pdf, epub, mobi or docx formats.
This application usually comes as a java applet web application. In this study the vapor pressures of seven frequently industrially used alkanolamines diethanolamine, n. Covering the properties of over 8,200 compounds, this volume, written by the worlds leading authority on chemical engineering, is more comprehensive and thorough than any other book of its kind. The yaws handbook of vapor pressure 2nd edition elsevier. Antoine coefficients kindle edition by yaws, carl l download it once and read it on your kindle device, pc, phones. The content of this database presents a compilation of results for vapor pressure using the antoine equation, and contains an extensible, searchable table with. Bubble point temperatures or pressures dew point temperatures or pressures vapor liquid equilibrium and many other processes, for distillation columns, phase separators, and other mass transfer process equipment. The antoine equation cannot be used for the entire vapor pressure range from the triple point to the critical point because it is not flexible enough. The antoine equation is derived from the clausiusclapeyron relation.
The equation was presented in 1888 by the french engineer louis charles antoine 18251897. The properties of antoine coefficients contained in this volume are useful when calculating. Carl l yaws increased to include over 25000 organic and inorganic. Vapor pressure calculation using antoine coefficients.
The antoine equation is a class of semiempirical correlations describing the relation between. Antoine coefficients, edition 2 ebook written by carl l. Download it once and read it on your kindle device, pc, phones or tablets. Antoine coefficients for vapor pressure of the elements. Yaws november 1, 2006 vapor pressure is important to engineers throughout the chemical process industries cpi.
Arranged by molecular formula, with indexes by name and cas registry number. University of kwazulunatal, durban campus for the degree doctor of philosophy chemical engineering december 2006. Physical properties for more than 54,000 organic and inorganic chemical compounds, coverage for c1 to c100 organics and ac to zr inorganics, edition 2 ebook written by carl l. Vapor pressure of the componants by antoine coefficients. The yaws handbook of vapor pressure, second edition. Table of 25,000 organic and 525 inorganic compounds showing. Antoine coefficients, 2nd edition delivers the most comprehensive and. Increased to incorporate over 25,000 natural and inorganic compounds, the yaws instruction manual of vapor strain. The yaws handbook of vapor pressure cern document server. Table of 25,000 organic and 525 inorganic compounds showing antoine coefficients a,b,c for vapor pressure as function of temperature. The antoine equation is a class of semiempirical correlations describing the relation between vapor pressure and temperature for pure substances. The properties listed in the yaws handbook of vapor pressure. Antoine coefficients, second edition delivers the most comprehensive and practical database source for todays petrochemical.
Generalization and prediction of coefficients of normal alkanes article pdf available in journal of materials science and chemical engineering 54. This site is like a library, use search box in the widget to get ebook that you want. Download for offline reading, highlight, bookmark or take notes while you read the yaws handbook of vapor pressure. Understanding antoine coefficients for vapor pressure leads to numerous critical engineering applications such as pure components in storage vessels, pressure relief valve design, flammability limits at the refinery, as well as environmental emissions from exposed liquids, making data to efficiently calculate these daily challenges a. Understanding antoine coefficients for vapor pressure leads to numerous critical engineering applications such as pure components in storage vessels, pressure relief. Purchase the yaws handbook of vapor pressure 2nd edition. The antoine vaporpressure correlation also referred to as the antoine equation and. The cylinder can be used until its absolute pressure drops to 1.
Development and critical evaluation of group contribution methods for the estimation of critical properties, liquid vapour pressure and liquid viscosity of organic compounds by yash nannoolal b. Yaws handbook of antoine coefficients for vapor pressure 2nd. Increased to include over 25,000 organic and inorganic compounds, the yaws handbook of vapor pressure. Antoine coefficients for vapor pressure of the elements by carl l. Whether working in environmental, chemical, or safety engineering, or chemistry, this book is invaluable, a handy reference for the practicing engineer or textbook for the engineering or chemistry student. Carl yaws is the worlds foremost authority on vapor pressure and the properties of chemicals and he again proves it in this follow up to his important work published in 2005 by gpc books, the yaws handbook of physical properties of hydrocarbons and chemicals. Mathematics, vapor pressure, handbooks, manuals the yaws handbook of vapor pressure open library. Regular article physical chemistry research published by the iranian chemical society.
Vapor pressure and boiling point the vapor pressure of a liquid is related to its heat of vaporization, h vap, through the clausiusclapeyron equation. The yaws handbook of physical properties for hydrocarbons. Estimate the vapour pressure at 45 o c using a the antoine. Yaws, 9781933762104, available at book depository with free delivery worldwide. Mar 12, 2015 increased to include over 25,000 organic and inorganic compounds, the yaws handbook of vapor pressure. Handbook of vapor pressure inorganic compounds and. Understanding antoine coefficients for vapor pressure leads to numerous critical engineering applications such as pure components in storage vessels, pressure. Regular article physical chemistry research published by the. The problem at hand is the fitting of experimental data to equations used to represent the vapor pressure. A theoretical basis for the antoine vapor pressure equation. B and c are empirically derived constants known as the antoine coefficients. Antoine coefficients, 2 nd edition supplies the main complete and useful database resource for todays petrochemical. Bubble point temperatures or pressuresdew point temperatures or pressuresvaporliquid equilibriumand many other processes, for distillation columns, phase separators, and other mass transfer process equipment.
In order to navigate out of this carousel please use your heading shortcut key to navigate to the next or. A rangefree method to determine antoine vaporpressure heat. Vapour pressures depend strongly on the temperature and vary widely with different compounds due to differences in molecule molecule interactions. Click download or read online button to get the yaws handbook of vapor pressure book now. C9 vapor pressure c10 enthalpy of vaporization c11 enthalpy of formation c12 gibbs energy of formation c solubility in salt water c14 solubility of organic compounds in water as a. Vapour pressure the vapor pressure p is the pressure of the vapor of a compound in equilibrium with its pure condensed phase solid or liquid. Carl l yaws increased to include over 25,000 organic and inorganic compounds, the yaws handbook of vapor pressure. Development and critical evaluation of group contribution. Understanding antoine coefficients for vapor pressure leads to numerous critical engineering applications such as.
We begin with a list of the temperatures in celcius at which the vapor pressure has been measured. The vapor pressure and vaporization enthalpy results obtained are compared with data calculated by the program pert2 and antoine constants estimated by kudchadker and zwolinski. Calculates vapor pressure of a chemical using the antoine equation. Vapor pressure calculations using antoine coefficients. Understanding antoine coefficients for vapor pressure leads to numerous critical engineering applications such as pure components in storage vessels, pressure relief valve.
290 1552 607 226 212 810 467 1228 741 849 73 443 110 1120 895 10 399 471 817 291 1542 326 1554 845 1313 1112 205 647 629 1017 1419 621 1135 653 917 465 338 1095 901 234 1183